A unique inside look at the electronic structure of a highly touted metal-organic framework (MOF) as it is adsorbing carbon dioxide gas should help in the design of new and improved MOFs for carbon capture and storage. Researchers with the U.S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab) have recorded the first in situ electronic structure observations of the adsorption of carbon dioxide inside Mg-MOF-74, an open metal site MOF that has emerged as one of the most promising strategies for capturing and storing greenhouse gases.
Mg-MOF-74 is an open metal site MOF whose porous crystalline structure could enable it to serve as a storage vessel for capturing and containing the carbon dioxide emitted from coal-burning power plants. (Credit: National Academy of Sciences)source: internet