The attraction between the Na+ and Cl− ions in the solid is so strong that only highly polar solvents like water dissolve NaCl well. When dissolved in water, the sodium chloride framework disintegrates as the Na+ and Cl− ions become surrounded by the polar water molecules. These solutions consist of metal aquo complex with the formula [Na(H2O)8]+, with the Na-O distance of 250 pm. The chloride ions are also strongly solvated, each being surrounded by an average of 6 molecules of water. Solutions of sodium chloride have very different properties from pure water. The freezing point is −21.12 °C (−6.02 °F) for 23.31 wt% of salt, and the boiling point of saturated salt solution is near 108.7 °C (227.7 °F). From cold solutions, salt crystallises as the dihydrate NaCl•2H2O.
